CH 431 Physical Chemistry I
Spring Session 2003
Class Time:
Problem Period: 401 Th 11:20-12:35 (Dab 330)
Instructor:
Dr. Stefan Franzen, Dabney 714, Email:
Stefan_Franzen@ncsu.edu
Office Hours: W,F 10-11
Text:
Physical Chemistry, A Molecular Approach 5th Edition, McQuarrie and Simon, University Science Books,
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Date |
Topic |
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Recommended Problems |
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1. Jan 9 |
Macroscopic vs. Microscopic |
26.1, 17.1,27.1-2 |
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2. Jan 14 |
Properties of Gases |
16.1, 25.1,25.2 |
16-11,2,3,4,5,6,7 |
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3. Jan 16 |
Real Gases/Corresponding
States |
16.2 – 16.7 & H |
16-13,16-25 |
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4. Jan 24 |
Partition Function |
17.1 – 17.5 |
16-31 - 16-33 |
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5. Jan 28 |
Average Properties |
17.6 – 17.8, 18.1 |
17-11,12,13,14 |
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6. Jan 30 |
The First Law |
19.1 – 19.4 |
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7. Feb 4 |
Heat, Work, and Energy |
19.5 – 19.10 |
19-2,4,5,6,7 |
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13 Feb 6 |
Mid-term I |
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18 Feb 11 |
Thermochemistry |
19.11 |
19-13 to 19-20 |
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8. Feb 13 |
Entropy and the 2nd
Law |
19.12 |
19-25,26,35,36&39 |
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9. Feb 18 |
Second Law Applications |
20.1 - 20.7 & I |
I-1,4,6,8,10 |
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10. Feb 20 |
Entropy and the Third Law |
21.1 - 21.9 |
H-11, 20-2,3,4 |
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11. Feb 25 |
Gibbs Free Energy |
22.1 - 22.2 |
22-1, 22-8,
22-9, 22-12 |
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12. Feb 27 |
Gibbs Energy Applications |
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13.
Mar 4 |
Second
Law Applications |
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14. Mar 6 |
Maxwell Relations |
22.3 - 22.7 and J |
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16 Mar 18 |
Phase
Equilibria Phase
Diagrams |
23.1 - 23.3 |
23-2,
23-27, 23-28, 23-29, 23-36 |
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15. Mar 20 |
The Clausius-Clapeyron
Eqn. |
23.4 , 23.5 |
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16. Mar 25 |
Solutions – Real and Ideal |
24.1 - 24.5 |
24-22, 24-26, 24-29, 24-48 |
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17. Mar 27 |
Activity |
24.6 |
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18. Apr 1 |
Mid-term II |
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19. Apr 3 |
Gibbs-Duhem
Equation |
24.7 - 24.9 |
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20. Apr 8 |
Colligative Properties |
25.1 - 25.5 |
25-1, 25-2, 25-3, 25-4, 25-40, 25-42, 25-43, 25-44 |
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21. Apr 10 |
Gibbs Energy |
26.1 – 26.6 |
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22. Apr 15 |
Standard States |
26.7 - 26.12 |
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23. Apr 22 |
Debye – Huckel Theory |
25.6 - 25.7 |
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24. Apr 24 |
Special Topics |
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25. Apr 29 |
Special Topics |
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26. May 1 |
Review |
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18 Dec |
Final Exam |
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Grades will be based as follows: There
will be +/- grading.
Quizzes and Homework 300 pts
Mid-Terms 400
pts
Final Exam 300
pts
Semester Total 1000 pts
The Final Exam can substitute for one mid-term (i.e.
500 pts) in case of excused absence.